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Photocatalytic production of hydrogen and methane from glycerol reforming over Pt/TiO2–Nb2O5
저자
Iervolino G.,Vaiano V.,Murcia J.J.,Lara A.E.,Hernández J.S.,Rojas H.,Navío J.A.,Hidalgo M.C.
학술지명
International Journal of Hydrogen Energy
출판/발행연도
2021
주제
요약
본 연구에서는 TiO2–Nb2O5에 담지된 백금 촉매를 사용하여 UV 조사 하에서 글리세롤 수용액으로부터 수소 및 메탄을 광촉매적으로 생산하는 것을 조사했습니다. Ti:Nb 비율이 다른 촉매를 제조하여 낮은 밴드갭, 백금 나노 입자의 분산, 다양한 백금 종 형성과 같은 향상된 물리화학적 특성을 확인했으며, 최적 조건에서 4시간 UV 조사 후 각각 6657 μmol/L의 수소와 194 μmol/L의 메탄 생산량을 달성했습니다. 또한 D2O를 사용한 실험을 통해 수소 생산에서 물 분자의 역할을 확인했습니다.
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