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Cationic Ring-opening Polymerization of Epichlorohydrin Using Hydroxyl-terminated Polybutadiene as an Initiator Followed by the Azidation of the Resulting Block Copolymer
Author
민병선, 정혜흔
Journal Title
폴리머
Publication Year
2018
Topics
Summary
Epichlorohydrin (ECH) was polymerized via cationic ring-opening polymerization using hydroxyl-terminated polybutadiene as an initiator, favoring an activated monomer mechanism. The resulting block copolymer PECH-PB-PECH was separated by fractional precipitation. However, complete azidation of PECH-PB-PECH was not achieved due to entanglement with unreacted polymers during high-temperature azidation.
Journal Influence
[폴리머]
- CiteScore
- 0.9
- ES
- 0.00016
- JCI
- 0.12
- JCR
- 0.6
- KCI
- 0.19
- SJR
- 0.162
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